Doomed couple: Angelina Jolie and Billy Bob Thornton
Wedding date: May 5, 2000
Angelina celebrated the completion of a three-day stint at UCLA Medical Center's Neuropsychiatric Institute, where she'd been recovering from a nervous breakdown, by marrying her "Pushing Tin" co-star at the Little Church of
the West. Shocking (or not!), Billy was technically still involved with Laura Dern at the time. The controversial couple, who exchanged vials of their blood rather than wedding bands, called it quits in May 2003.
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